{"id":42,"date":"2015-12-23T00:54:17","date_gmt":"2015-12-22T22:54:17","guid":{"rendered":"http:\/\/blog.metu.edu.tr\/ademet\/?page_id=42"},"modified":"2016-09-28T17:48:34","modified_gmt":"2016-09-28T14:48:34","slug":"smart-metallo-polymers","status":"publish","type":"page","link":"https:\/\/blog.metu.edu.tr\/ademet\/research\/smart-metallo-polymers\/","title":{"rendered":"Smart Metallo-polymers"},"content":{"rendered":"<p><a href=\"https:\/\/blog.metu.edu.tr\/ademet\/files\/2015\/12\/smart-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"size-medium wp-image-178 alignleft\" src=\"https:\/\/blog.metu.edu.tr\/ademet\/files\/2015\/12\/smart-1-300x215.png\" alt=\"smart-1\" width=\"300\" height=\"215\" \/><\/a>The development of conjugated polyelectrolyte LECs represents a shift of complexity away from device fabrication and into the domain of chemical synthesis, allowing the deep well of synthesis knowledge to be drawn upon and applied to the creation of materials and devices that solve a clear and present problem: the generation of new, energy-efficient lighting and display technologies. The use of chemical self-assembly as a synthetic technique can further simplify materials preparation by shifting intellectual effort away from designing molecules and toward the design of chemical systems that are capable of self-assembling in such a way as to express the desired materials properties.\u00a0<span class=\"current-selection\">C<\/span><span class=\"ff7 fs1\"><span class=\"current-selection\">onstitutionally<\/span> <span class=\"current-selection\">dynamic<\/span> <span class=\"current-selection\">polymers\u00a0<\/span><\/span><span class=\"current-selection\">can<\/span> <span class=\"current-selection\">reconfigure<\/span> <span class=\"current-selection\">their\u00a0<\/span><span class=\"current-selection\">structures<\/span> <span class=\"current-selection\">and<\/span> <span class=\"current-selection\">properties<\/span> <span class=\"current-selection\">in<\/span> <span class=\"current-selection\">response<\/span> <span class=\"current-selection\">to<\/span> <span class=\"current-selection\">stimuli<\/span> <span class=\"current-selection\">in<\/span> <span class=\"current-selection\">ways<\/span> <span class=\"current-selection\">that\u00a0<\/span><span class=\"current-selection\">conventional<\/span> <span class=\"current-selection\">polymers<\/span> <span class=\"current-selection\">cannot. <\/span><\/p>\n<p><span class=\"current-selection\">In our group, w<\/span><span class=\"current-selection\">e<\/span> <span class=\"current-selection\">are investigating the<\/span>\u00a0<span class=\"current-selection\">self-assembly\u00a0<\/span><span class=\"current-selection\">of<\/span> <span class=\"\"><span class=\"current-selection\">dynamic-covalent<\/span><\/span> <span class=\"current-selection\">metallopolymers,\u00a0<\/span><span class=\"current-selection\">which<\/span> are capable of undergoing<span class=\"current-selection\">\u00a0<\/span><span class=\"current-selection\">reversible<\/span> <span class=\"current-selection\">structural<\/span> <span class=\"current-selection\">rearrangement<\/span> <span class=\"current-selection\">in<\/span> <span class=\"current-selection\">response<\/span> <span class=\"current-selection\">to stimuli such as\u00a0<\/span><span class=\"current-selection\">temperature,<\/span> <span class=\"current-selection\">electric<\/span> <span class=\"current-selection\">field<\/span>\u00a0etc.<span class=\"current-selection\">,<\/span><\/p>\n<p>Read more&#8230;<\/p>\n<p><a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201404186\/epdf\">http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201404186\/epdf<\/a><\/p>\n<p><a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja308055s\">http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja308055s<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>The development of conjugated polyelectrolyte LECs represents a shift of complexity away from device fabrication and into the domain of chemical synthesis, allowing the deep well of synthesis knowledge to be drawn upon and applied to the creation of materials <a class=\"more-link\" href=\"https:\/\/blog.metu.edu.tr\/ademet\/research\/smart-metallo-polymers\/\">Read More &#8230;<\/a><\/p>\n","protected":false},"author":3883,"featured_media":0,"parent":17,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":"","_links_to":"","_links_to_target":""},"class_list":["post-42","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/blog.metu.edu.tr\/ademet\/wp-json\/wp\/v2\/pages\/42","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/blog.metu.edu.tr\/ademet\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/blog.metu.edu.tr\/ademet\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/blog.metu.edu.tr\/ademet\/wp-json\/wp\/v2\/users\/3883"}],"replies":[{"embeddable":true,"href":"https:\/\/blog.metu.edu.tr\/ademet\/wp-json\/wp\/v2\/comments?post=42"}],"version-history":[{"count":0,"href":"https:\/\/blog.metu.edu.tr\/ademet\/wp-json\/wp\/v2\/pages\/42\/revisions"}],"up":[{"embeddable":true,"href":"https:\/\/blog.metu.edu.tr\/ademet\/wp-json\/wp\/v2\/pages\/17"}],"wp:attachment":[{"href":"https:\/\/blog.metu.edu.tr\/ademet\/wp-json\/wp\/v2\/media?parent=42"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}